Flammability limits
·Lower explosive limit, LEL (also LFL)
-The minimum concentration of vapor in air below
which a spread of flame does not occur when the
vapor is in contact with a source of ignition
Acetone LEL=2.5%
·Upper explosive limit, UEL (also UFL)
-The maximum concentration of vapor in air above
which a spread of flame does not occur when the
vapor is in contact with a source of ignition.
-Acetone UEL=12.8%
·Explosive range (also flammable range)
- The spread between the LEL and UEL
- Acetone explosive range = 2.5-12.8%
Relationship between toxicity and flammability
TLV ; PEL; IDLH ; (LEL ; UEL) ; O2 deficient
1-100 ppm 1000-5000 ppm (1-20 percent)
Toluene Example:
TLV=50 ppm,
·PEL =200 ppm,
·IDLH= 500 ppm,
• LEL= 1.1%,
·UEL 7.1%
Definitions
• Ignition temperature
- The temperature at which ignition (production of flame) and burning will be continued after the source of ignition or the source of heat is removed
• Flash point
-The lowest temperature at which enough vapor is given off near the surface of a liquid to produce a flammable mixture with air.
• Flammable liquid
- Liquids with a flash point below 100 F
• Combustible liquid
- Liquids with a flash point 100 F or greater
Fire Types
• Flame fire
- Gases or vapors
- High burning rate
• Surface fire
- Burning rate may be slow
• Explosion π₯
- An event leading to a rapid increase of pressure
Explosions
• Deflagration
- Combustion wave propagates at subsonic velocity
• Detonation
- Combustion wave propagates at supersonic
velocity
• Gas or vapor explosion
- Combustion of pre-mixed gas or vapor
• Dust explosion
- Finely divided solids, suspended in air
• BLEVE
- Boiling Liquid Expanding Vapor Explosion
- Flash evaporation after vessel rupture
- May not involve combustion
Chemistry of Fire
• Combustion
- Rapid oxidation
• Combustion components
- Oxygen
• Atmosphere (21%)
• Chemical oxidizers
- Fuel
• Solids
-Surface-to-mass ratio
• Gaseous
• Liquids (vapors)
• BGases
• Combustion components (cont.
— Heat
· Heat of combustion
· Other sources of heat: (ignition)
- Chemical reactions
• Decay
• Slow oxidation
- Electricity
• Arcing
• Resistance
— Mechanical friction
- Chemical Chain Reaction
• Propagated by free radicals
Products of combustion
· Heat
· Acid Gases
-Hydrogen Chloride
-Sulfur dioxide
·Soot, smoke
·Carbon dioxide
·Carbon monoxide
- Incomplete combustion
• Nitrogen oxides
·Ammonia
· Acrolein
·Hydrogen cyanide
·Metal Fumes
• Hydrogen sulfide
·Phosgene
The Fire Triangle
· Four components:
- Oxygen
- Heat
- Fuel
- Reaction
• Removing any component stops the fire
Extinguishing a fire
• Cooling - Applying water
• Removing Fuel
- Shut off supply to gas or liquid fires
- Pump liquid from burning tanks
• Limiting oxygen
- Mechanical smothering
- Foam
- Displace oxygen with inert gas
• Interrupt chain reaction
- Capture free radicals using an extinguishing agent
Fire olassification
Class A
- Ordinary combustibles
-Wood, paper, rubbish
-Extinguish with water
Class B
- Flammable liquids
-Water may aggravate a burning liquid fire
-Extinguish with foam, chemical agents
Class C
- Fires in electrical equipment
- Use non-conductive extinguishing agent
Class D
- Combustible metal fires
- Extinguish by smothering with dry powder
- Water will cause burning metals to explode
• Special categories
Extinguishing agents
• Water
-Removes heat from a fire
-Streams, spray or fog
- Best for Class A fires
- Not for electrical or combustible metal fires
·Water mist may be used on electrical fires. These are special fire extinguishers, filled with distilled water, that produce a fine mist (no solid stream of water)
·Foam
- Excludes oxygen from burning liquid fires
- Aqueous Film Forming Foam (AFFF)
- Fire can re-ignite if foam breaks down
• Inert Gases
- Displaces oxygen
-Carbon dioxide, nitrogen
• Halogenated Hydrocarbons
- Inhibit chain reactions
- HALON (bromo-fluoro-chloro-hyrdrocarbons)
- Carbon tetrachloride (historically)
- Ozone depleting
– New, more ozone-friendly agents are available
• Dry Chemical
- Inhibit chain reactions
- Sodium or potassium bicarbonate
-For Class B or C fires
• Multipurpose Dry Chemical
- Monoammonium phosphate
- For Class A, B, or C fires
- Excludes oxygen by coating surfaces
• Dry Powder
- Excludes oxygen from burning metal
- Sodium chloride, graphite